Stephen Bunting is looking for his first European tour title of the season.
It comes after Bunting wrapped up the curtain on the league stage of the Premier League Darts season, beating Luke Humphries 6-3 to win in Sheffield.
Michael van Gerwen, James Wade, and Gian van Veen are also in action at the WT Energiesysteme Arena.
Following the conclusion of round two, the remaining 16 players will return to battle it out from 11am BST on Sunday.
The tournament reaches its climax with the quarter-finals, semi-finals and final in a bumper evening session, which begins from the earlier time of 5pm.
Gerwyn Price withdrew from the tournament earlier this week and was replaced by Christian Kist, who will take on Englishman Ryan Joyce.
Sunday May 24
Afternoon Session (11am)
Round Three
Gian van Veen vs Kevin Doets
Ryan Searle vs Kim Huybrechts
Stephen Bunting vs Rob Cross
Ryan Joyce vs Jermaine Wattimena
Michael van Gerwen vs Damon Heta
Ricardo Pietreczko vs Ross Smith
James Wade vs Wessel Nijman
Cameron Menzies vs Martin Schindler
Evening Session (5pm)
Quarter-Finals
Semi-Finals
Final
Sunday's games played in Draw Bracket order
Saturday May 23
Round Two
Afternoon Session
Jermaine Wattimena 6-5 Bradley Brooks
Damon Heta 6-2 Niels Zonneveld
Kevin Doets 6-5 Luke Woodhouse
Ricardo Pietreczko 6-5 Danny Noppert
Ross Smith 6-3 Joe Cullen
Rob Cross 6-2 Mike De Decker
Wessel Nijman 6-5 William O'Connor
Cameron Menzies 6-4 Josh Rock
Evening Session
Kim Huybrechts 6-5 Chris Dobey
James Wade 6-0 Dave Chisnall
Ryan Searle 6-3 Charlie Manby
Ryan Joyce 6-2 Christian Kist
Gian van Veen 6-3 Connor Scutt
Michael van Gerwen 6-5 Madars Razma
Stephen Bunting 6-2 Krzysztof Ratajski
Martin Schindler 6-5 Karel Sedlacek
Friday May 22
Round One
Afternoon Session
Ryan Joyce 6-2 Jeffrey Sparidaans
Connor Scutt 6-1 Finn Behrens
Madars Razma 6-2 Gyorgy Jehirszki
Andrew Gilding 4-6 Bradley Brooks
Cameron Menzies 6-5 Michael Unterbuchner
Karel Sedlacek 6-0 Johan Engstrom
Ricardo Pietreczko 6-2 Maik Kuivenhoven
Niels Zonneveld 6-2 Keane Barry
Evening Session
Dave Chisnall 6-3 Liam Maendl-Lawrance
Kevin Doets 6-0 Tom Bissell
William O'Connor 6-2 Paul Krohne
Joe Cullen 6-5 Chris Landman
Dirk van Duijvenbode 5-6 Rob Cross
Krzysztof Ratajski 6-4 Cristo Reyes
Niko Springer 3-6 Charlie Manby
Daryl Gurney 2-6 Kim Huybrechts
Who will win this year's Premier League Darts? Watch the action every single Thursday until finals night in London on May 28 on Your Site. .